三苯基磷中铑的测定(ICP-AES法)  

Determination of Rhodium in Triphenylphosphine (ICP-AES method)

作　　者：张岩[1] 梁景程[1] 杨慧娟[1] 高文莉[1] 

机构地区：[1]大庆石化公司研究院,黑龙江大庆163714

出　　处：《辽宁化工》2006年第9期552-554,共3页Liaoning Chemical Industry

摘　　要：采用等离子发射光谱法测定三苯基磷中铑的含量，采用直接湿法和高压硝化罐两种方法处理样品，并选择了合适的分析谱线和积分时间，方法简便，准确，快速，回收率为95％～104％，相对标准偏差〈2．0％，检出限为0．0095μg／g。Rhodlium content in triphenylphosphine was determined with plasma emission spectrography, Sample was cured in direct wet method and high pressure nitrating pot method, Suitable analysis spectral line and integral time were selected. This method was simple, accurate and quick. The recovery rate was 95 % - 104 % The relative standard deviation was less than 2.0% and detection Limit was 0.009 5μg/mL.

关 键 词：三苯基磷 铑 等离子 消化罐 

分 类 号：O657.3[理学—分析化学]