Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO_ 3)_ 2  

作　　者：WEI Xian-yin HUANG Ru-dan YU Li-qiong ZHU Qin-lei ZHANG Zhong-qiang LIU Li-ping 

机构地区：[1]Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, P. R. China [2]Department of Chemistry, Hengshui University, Hengshui 053000, P. R. China

出　　处：《Chemical Research in Chinese Universities》2006年第5期665-668,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos. 20476011 and 20371007).

摘　　要：The self-assembly of clusters in inorganic systems is an interesting subject. The self-assembly of big molecules has been well established in biological systems. In addition, the coordination chemistry of metal-sulfur-nitrogen cluster complexes has been a very active and attracting field for many years as a result of the novelty and versatility of the crystal structures and reactivities of such clusters, as well as their potential applications as the models for the active sites in non-heme proteins. At the same time, there is currently considerable interest in the formation of metal complexes with heterocyclic ligands because of the diverse characteristics of ligands and their consequential wide range of applications.The self-assembly of clusters in inorganic systems is an interesting subject. The self-assembly of big molecules has been well established in biological systems. In addition, the coordination chemistry of metal-sulfur-nitrogen cluster complexes has been a very active and attracting field for many years as a result of the novelty and versatility of the crystal structures and reactivities of such clusters, as well as their potential applications as the models for the active sites in non-heme proteins. At the same time, there is currently considerable interest in the formation of metal complexes with heterocyclic ligands because of the diverse characteristics of ligands and their consequential wide range of applications.

关 键 词：Self assembly Tetranuclear cluster Zinc complex Crystal structure 

分 类 号：O614.241[理学—无机化学] O641.4[理学—化学]