N,N'-二甲基-N,N'-二辛基丙二酰胺萃取铀髩的研究  

Extraction of U(Ⅵ) with N,N′-dimethyl-N,N′-dioctylmalonamide

作　　者：张振伟[1] 崔玉[1] 孙国新[1] 孙思修[2] 

机构地区：[1]济南大学化学化工学院,济南250022 [2]山东大学化学化工学院,济南250100

出　　处：《无机化学学报》2006年第10期1867-1870,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20301008);山东省自然科学基金(No.Q2003B01)资助课题

摘　　要：The novel unsymmetrical extractant N,N′-dimethyl-N,N′-dioctylmalonamide (DMDOMA) was prepared by reaction of diethyl malonate with N-methyl octanamine. The extraction mechanism and the behavior of uranyl nitrate with DMDOMA employed cyclohexane as diluent were studied. The effects of concentrations of nitric acid, sodium nitrate, extractant and also the temperature on the extraction were considered. The stoichiometry of the extracted species is and the coordination of extracted species was suggested based on the IR data. The value of ΔH of extraction is -26.9 ± 0.80 kJ·mol-1. The value of the apparent extraction constant is 133.88 ± 17.92, which shows that the optimization of extractant structure improves the extractability of malonamide for uranyl nitrate.The novel unsymmetrical extractant N,N＇-dimethyl-N,N＇-dioctylmalonamide （DMDOMA） was prepared by reaction of diethyl malonate with N-methyl octanamine. The extraction mechanism and the behavior of uranyl nitrate with DMDOMA employed cyclohexane as diluent were studied. The effects of concentrations of nitric acid, sodium nitrate, extractant and also the temperature on the extraction were considered. The stoichiometry of the extracted species is and the coordination of extracted species was suggested based on the IR data. The value of △H of extraction is -26.9 ± 0.80 kJ ·mol^-1. The value of the apparent extraction constant is 133.88 ± 17.92, which shows that the optimization of extractant structure improves the extractability of malonamide for uranyl nitrate.

关 键 词：N N′-二甲基-N N′-二辛基丙二酰胺 萃取 硝酸铀酰 环己烷 

分 类 号：O614.4[理学—无机化学]