等离子体聚合正丁胺  

PLASMA POLYMERIZATION OF N-BUTYLAMINE

作　　者：颜永红[1] 曾云[1] 彭景翠[1] 陈迪平[1] 陈小华[1] 向建南[1] 张伟强[1] 王柯敏[1] 王彬锋[1] 

机构地区：[1]湖南大学应用物理系,湖南大学化工系

出　　处：《微细加工技术》1996年第3期66-70,共5页Microfabrication Technology

基　　金：湖南省自然科学基金

摘　　要：首次在等离子体状态下将正丁胺单体聚合成聚正丁胺薄膜，这种聚合反应可在一定工艺范围内发生。由元素分析的结果发现，在聚合反应过程中有氢元素逸出，并且主要是Ｃ－Ｈ上氢元素的逸出，从而使得聚合物上Ｃ／Ｈ比增大。热稳定性和溶解性实验结果表明：聚正丁胺薄膜具有高度支化、交联的结构，性能稳定，不溶不融。红外光谱分析表明，该聚正丁胺薄膜中有胺基存在。For the first time, the thin organic polymer films of N-Butylamine were prepared by Plasma polymerization. This kind of polymer reaction can take place in a certain technology scope. Studies of elemental analysis indicates that there is a escape of hydrogen element in this polymerization reaction. The hydrogen element escalped is mainly hydrogen in the C─AH bond. So the rate of C/H increases in the polymer films. The result of ed,eriments shows that these polymer films have a very highly branched and cross linked structure with good resistance to heat and erosion. The analysis of IR spectrum indicates that the amino-group exists in the polymer films. of N-Butylamine.

关 键 词：等离子体 正丁胺 聚正丁胺 

分 类 号：TQ323.6[化学工程—合成树脂塑料工业]