具有双光子活性的蓝色发光材料的合成  

Synthesis of an Blue Fluorescence Compound with Two-photon Property

作　　者：孙梅[1] 丁大勇 胡寒梅[1] 周海鸥[1] 田玉鹏[3] 

机构地区：[1]安徽建筑工业学院材料科学与工程系,合肥230022 [2]合肥市第二十四中学 [3]安徽大学化学化工学院

出　　处：《应用化学》2006年第8期933-935,共3页Chinese Journal of Applied Chemistry

基　　金：安徽省教育厅自然科学研究项目(2005KJ327ZC);安徽建筑工业学院硕博启动基金资助项目(04-011)

摘　　要：合成了一种具有双光子活性的蓝色发光材料9,10-二咪唑甲基蒽,通过元素分析、电喷雾质谱、1H NMR和红外对其进行表征。测试了紫外吸收光谱、单光子荧光光谱、量子产率、单光子荧光寿命和双光子荧光光谱。双光子吸收截面为17×10-50cm4.s.photon-1,结果表明,是具潜在应用前景的双光子激发蓝光发光材料。A novel blue fluorescence compound with two-photon property was synthesized. The structure of the compound was characterized by elemental analysis, electron-spray mass spectra, 1^H NMR, and IR spectra. UY-Yis absorption, one-photon induced fluorescence, one-photon fluorescence quantum yield, onephoton fluorescence lifetime and two-photon induced fluorescence were experimentally studied. The two-photon absorption cross-section is as high as 17 ×10^-50 cm4 · s · photon^-1. It is a potential blue emission material.

关 键 词：双光子 荧光 蓝色发光材料 

分 类 号：O625[理学—有机化学]