克劳修斯不等式证明的一点补充  

Supplement to the proof of the Clausius inequality

作　　者：马春曦[1] 朱元海[1] 桑希勤[1] 

机构地区：[1]大庆石油学院化学化工学院,黑龙江大庆163318

出　　处：《大庆石油学院学报》2006年第5期93-95,共3页Journal of Daqing Petroleum Institute

摘　　要：补充了由卡诺定理导出二热源克劳修斯不等式的过程中存在的不足,指出把任意不可逆循环分解成无限多不可逆微卡诺循环之和,并据此证明任意不可逆过程的克劳修斯不等式在理论上是不严格的,建议采用较严格的费米法.The incompleteness of the proof of Clausius Inequality of two heat resources in current course of physical chemistry is illustrated and supplemented.It is not strict to approximate an actual irreversible cycle by a large amount of infinitesimal irreversible Carnot cycles for deducting its inequality of Clausius,and Fermi method is suggested.

关 键 词：克劳修斯不等式 熵 温标 

分 类 号：O642.11[理学—物理化学]