原位缩聚合成含聚芳酰胺／酯的微相复合物 Ⅴ．共聚酰胺与聚砜的微相复合物制备  

Aromatic polyamide (or polyester)-containing microcomposites by in-situ polycondensation

作　　者：黄双武 吴美琰[2] 张树范[2] 

机构地区：[1]美光半导体亚洲有限公司,新加坡339942 [2]中国科学院化学所,北京100080

出　　处：《合成技术及应用》2006年第3期8-11,共4页Synthetic Technology & Application

摘　　要：用原位缩聚法合成了芳香-脂肪共聚酰胺与聚砜的徽相复合物(PAA／PSF)。初步结果表明:PAA／PSF微相复合物具有热致液晶性能;PAA的加入大大提高了微相复合物的力学性能。以PA30(PAA=29．5ω)为例,拉伸强度和模量分别提高到原来的2．5倍和3．5倍。The mierocomposites of aromatie-aliphatie eopolyamide with polysulfone （PAA/PSF） in-situ polyeondensation. The preliminary results showed that PAA/PSF mieroeomposites were synthesized by thermotropie liquid crystalline behaviors. The addition of PAA component greatly improved the mechanical properties of PAA/PSF systems. For example, the tensile strength and modulus of PAA/PSF microcomposites increased 2.5 times and 3.5 times that of PSF matrix polymer respectively when 29.5 % of PAA component was incorporated.

关 键 词：微相复合物 原位缩聚 芳香-脂肪共聚酰胺 聚砜 分子间相互作用 

分 类 号：TQ316.32[化学工程—高聚物工业]