四氯化碳催化加氢制氯仿反应中气体溶解度研究  

Study on Gas Solubility in Chloroform Preparation Reaction System over Catalytic Hydrogenation

作　　者：马珺 邵丽莉 许建帼[2] 

机构地区：[1]浙江巨化集团技术中心,衢州324004 [2]浙江工业大学浙西分校,衢州324006

出　　处：《化工设计》2006年第5期21-24,8,共5页Chemical Engineering Design

摘　　要：在123℃、4.2MPa的实验条件下,采用高压搅拌釜对H_2和HCl在四氯化碳、二氯甲烷、三氯甲烷和催化剂组成的反应体系中的溶解度进行研究,对9个取样点的数据经过回归处理和关联,得到H_2和HCl气体的亨利系数及气液平衡数据。Under the conditions of 123℃ and 4.2 MPa, study on the solubility of H2 and HCl in the reaction system which consists of carbon te trachloride, dichloromethane, trichloromethane and catalysts in a high-pressure stirred reactor. Henry' s coefficient and material balance data of H2 and HCl are obtained through data regression processing relationship of 9 sampling sites.

关 键 词：亨利系数 氢气 氯化氢 溶解度 

分 类 号：O643.32[理学—物理化学] O623.21[理学—化学]