重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物的合成及Tb^(3+)的发光  

Synthesis and Luminescence of Methyl-Phenacyl Sulfoxide Complexes with Heavy Rare Earth Perchlorate

作　　者：李文先[1] 其其格[1] 王宏胜[1] 秦彩花[1] 郭磊[1] 陈丽娟[1] 

机构地区：[1]内蒙古大学化学化工学院,内蒙古呼和浩特010021

出　　处：《光谱学与光谱分析》2006年第10期1802-1805,共4页Spectroscopy and Spectral Analysis

基　　金：内蒙古自治区自然科学基金(200308020104);内蒙古自治区教育厅科研基金(NJ322002);内蒙古大学"513"人才基金资助

摘　　要：合成了重稀土高氯酸盐甲基苯甲酰甲基亚砜配合物RE(ClO4)3.L5.C2H5OH(RE=Gd,Tb,Dy,Tm,Yb;L=C6H5COCH2SOCH3)。经元素分析、稀土络合滴定、摩尔电导及热重分析确定了配合物的组成,测定了配体及配合物的IR谱、1H NMR及铽配合物的磷光光谱、荧光激发和发射光谱,根据荧光发射光谱数据计算了铽配合物的各能级值。Abstract RE（ClO4）3·L5·C2H5OH（RE=Gd, Tb, Dy, Tm, Yb; L=C6H5COCH2SOCH3） complexes were synthesized. The composion of the complexes was determined by elemental analysis, coordination titration, molar conductivities, and TGA studies. The ligand and coordination compounds were studied by means of IR spectra, ^1H NMR, and the Tb（ Ⅲ ） coordination compound was studied by means of phosphorescence spectra, and fluorescence excitation and emission spectra. Each energy level of Tb^3＋ was calculated according to the fluorescent emission spectra results.

关 键 词：重稀土高氯酸盐 甲基苯甲酰甲基亚砜的配合物 合成 发光 

分 类 号：O614.3[理学—无机化学]