铕-铽-钆-六氟乙酰丙酮三元配合物的合成与温敏发光性质  

Synthesis and Temperature Sensitized Photoluminescence Property of Eu(Ⅲ)-Tb(Ⅲ)-Gd(Ⅲ) Hexafluoroacetylacetone Ternary Complex with Triphenylphosphine Oxide

作　　者：张雁[1] 赵钰[1] 李叶根[1] 盛夏[1] 胡全[2] 钱国栋[1] 

机构地区：[1]浙江大学材料科学与工程系硅材料国家重点实验室,杭州310027 [2]杭州师范学院药理教研室,杭州310018

出　　处：《高等学校化学学报》2006年第11期2009-2012,共4页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:50532030);教育部跨世纪优秀人才培养计划项目资助

摘　　要：合成了铕-铽-钆-六氟乙酰丙酮(HFA)三元配合物Eu0.4Tb0.4Gd0.2(HFA)3(TPPO)2(TPPO:三苯基氧化磷),其组成和结构经元素分析和红外吸收光谱确认;研究了三元配合物的发光性能,以及铽、钆离子对铕离子发光性能的影响.结果表明,配合物中存在着声子支助的Tb3+→Eu3+的能量转移,增强了Eu3+离子的室温特征荧光发射,且样品的发光颜色随温度的改变而变化,具有温敏特性.Ternary lanthanide hexafluoroacetylacetonate complex with triphenylphoshine oxide, Eu0.4Tb0.4Gd0. 2 （HFA） 3 （TPPO） 2 （ HFA = hexafluoroacetylacetonate, TPPO = triphenylphoshine oxide）, was synthesized and identified by elemental analysis and FTIR. The photoluminescence （PL） spectra were measured and the characteristic transitions of Eu^3＋ and Tb^3＋ were observed. Temperature dependent PL properties of the ternary complex were also studied as well as the influences of Tb^3＋ and Gd^3＋ ions on PL properties of Eu^3＋ ions. As a result, the phonon assisted energy transfer from Tb^3＋ ions to Eu^3＋ ions, which enhanced the characteristic fluorescence intensity of Eu^3＋ ions at room temperature, was observed, and the sample exhibits different luminescent colors at different temperatures. The decay curves from the ^5D0 level of europium ions were measured at various temperatures and the lifetimes were obtained from fitting the data. It is seen that the lifetime decreases with increase in temperature. The complex is promising for being used as temperature detector and thermal- sensitive probe.

关 键 词：稀土 三元配合物 温敏发光 声子支助能量转移 

分 类 号：O614[理学—无机化学] O657.33[理学—化学]