三维银配位聚合物[Ag_3(IN)_2(CF_3COO)]的水热合成与晶体结构  

Hydrothermal Synthesis and Crystal Structure of a Novel Three-dimensional Silver Coordination Polymer[Ag_(3)(IN)_(2)(CF_(3)COO)]

作　　者：田戈[1] 袁宏明[1] 陈岩[1] 李光华[1] 冯守华[1] 

机构地区：[1]吉林大学无机合成与制备化学国家重点实验室化学学院,长春130012

出　　处：《高等学校化学学报》2006年第11期2045-2047,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:20121103;20301007)资助

摘　　要：A three-dimensional silver coordination polymer,[(Ag3（IN）2(CF3COO))]（IN=Isonicotinic acid）,was synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction.The compound crystallizes in the triclinic space group P-1,with unit cell parameters a=0.918 48（5） nm,b=1.013 92（6） nm,c=1.067 05（6） nm,Z=2,R1=0.036 5,wR2=0.095 5.The Ag centers are bridged by the IN and CF3CO2 ligands to form three-dimensional structure.There are strong Ag-Ag bond interaction in the framework.A three-dimensional silver coordination polymer, [ Ag3 （IN） 2 （CF3COO） ] （ IN = Isonicotinic acid） , was synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. The compound crystallizes in the triclinic space group P-1, with unit cell parameters a = 0. 918 48 （5） nm, b = 1. 013 92（6） nm, c = 1. 067 05（6） nm, Z =2, R1 =0. （136 5, wR2 =0. 095 5. The Ag centers are bridged by the IN and CF3CO2 ligands to form three-dimensional structure. There are strong Ag-Ag bond interaction in the framework.

关 键 词：水热合成 晶体结构 银配位聚合物 

分 类 号：O614[理学—无机化学]