强制脉冲CVI沉积C纤维表面涂层的工艺研究  

Carbon Fiber Surface Coating by Forced Pressure-pulsed CVI

作　　者：周清[1,2] 董绍明[1] 张翔宇[1] 丁玉生[1,2] 黄政仁[1] 江东亮[1] 

机构地区：[1]中国科学院上海硅酸盐研究所 [2]中国科学院研究生院,北京100049

出　　处：《无机材料学报》2006年第6期1378-1384,共7页Journal of Inorganic Materials

基　　金：国家863项目(2002AA334040);上海市重大基础研究项目(04DZ14002)

摘　　要：以MTS/H_2为前驱物,采用强制脉冲CVI(FP-CVI)方法,进行了在C纤维表面沉积SiC涂层的研究,并探讨了其工艺过程．结果表明,在1000～1100℃和(5～25)kPa,沉积得到的β-SiC具有明显的(111)面取向,涂层均匀一致,厚度可控．在实验过程中,随着单次驻留时间和脉冲次数的增加,涂层厚度也随之增加,涂层厚度与脉冲次数成非线性关系．当脉冲次数为300时,C纤维表面沉积SiC层后其质量增加达到36．18％．A SiC coating was derived from a gaseous methyltrichlorosilane （MTS）/H2 precursor by forced pressure-pulsed CVI （FP-CVI） process at low temperatures and reduced pressure. In the present experiment, the FP-CVI process was studied, and the correlation between the coating thickness and the depositing conditions, i.e. the deposition temperature, the pressure, the deposition time per pulse and the pulse number was investigated. In 1000-1100℃ and （5-25）kPa, the homogeneous β-SiC coating synthesized has （111） orientation. The coating thickness increases as the holding time per pulse and the pulse number increase. It shows a nonlinear behavior between the coating thickness and the pulse number. When the pulse number reaches 300 in all, the mass increment is 36.18% after coating on the carbon fiber.

关 键 词：C纤维 SIC涂层 FP-CVI 

分 类 号：TB332[一般工业技术—材料科学与工程]