光敏剂2,4,7-三硝基-9-芴酮的合成与红外光谱表征  

Synthesis and spectral characterized of the photosensitizer 2,4,7-trinitro-9-fluorenone(TNF)

作　　者：李姝[1] 周志强[2] 

机构地区：[1]哈尔滨理工大学材料科学与工程学院,黑龙江哈尔滨150040 [2]东北林业大学理学院,黑龙江哈尔滨150040

出　　处：《化学工程师》2006年第10期7-8,20,共3页Chemical Engineer

基　　金：黑龙江省自然科学基金项目(E0328)国家自然科学基金项目(20302001)

摘　　要：本文以浓H2SO4,发烟HNO3,9-芴酮为原料,合成了光敏剂-2,4,7-三硝基-9-芴酮(TNF)。确定三硝基芴酮的最佳合成工艺为:反应时间:1．5h;反应温度:20-2℃;9-芴酮:硝酸-1:3．45。采用红外光谱法对原料和产物进行表征,从而确定了合成的最佳工艺路线和工艺条件。In the paper, the photosensitizer 2,4,7 - trinitm - 9 - fluorenone （TNF） was synthesized by using the 9 - fluorenone, sulfuric acid and fuming nitric acid as raw material. The product is a kind of photosensitizer, and it has photoconductivity functions, The best technology was determined as follows： action time： 1,5 h, temperature ：20 - 21℃, the ratio between 9 - fluorenone and nitric acid - 1 ： 3, 45. The constructs of raw material and product were characterized by IR. So, the optimum synthesis process conditions were obtained.

关 键 词：光敏剂 红外光谱法 合成 2 4 7-三硝基-9-芴酮 

分 类 号：O657.33[理学—分析化学]