Research on Effect of Four Natural Ultraviolet Light Absorbers on Photostabilization of Azadirachtin-A  

作　　者：TAN Wei-hong SONG Zhan-qian 

机构地区：[1]Institute of Chemical Industry of Forest Products/Key Laboratory on Forest Chemical Engineering, Chinese Academy of Forestry, Nanjing 210042, P.R.China

出　　处：《Agricultural Sciences in China》2006年第11期855-858,共4页中国农业科学（英文版）

基　　金：This project was supported by the National Natural Science Foundation of China(30500387);Natural Science Foundation of Jiangsu Province,China(BK2005008).

摘　　要：This study examined the photostabilization of Azadirachtin-A （Aza-A） when exposed to ultraviolet light in the presence of some natural absorbers. Aza-A extract solutions with and without natural UV light absorbers in methanol were applied onto the surface of glass slides. At particular intervals, the remaining concentration of Aza-A was analyzed by HPLC. Using first-order kinetic equation, the dissipation half-life values （DT^0） for the degradation of Aza-A under ultraviolet radiation were obtained. It indicated that the addition of ferulic acid, gallic acid, and rutin provided moderate degree of photostabilization of Aza-A and that addition of aloin provided the best photostabilization of Aza-A, among these UV absorbers studied. Photostabilization of Aza-A by different UV light absorbers appears to be due to the competitive energy absorption of UV photons by the absorbers molecules. The dissipation half-life values of Aza-A after irradiation under ultraviolet light suggested that the addition of aloin （in 1 ： 1 mol ratio） can provide better photostabilization of azadirachtin molecule.This study examined the photostabilization of Azadirachtin-A （Aza-A） when exposed to ultraviolet light in the presence of some natural absorbers. Aza-A extract solutions with and without natural UV light absorbers in methanol were applied onto the surface of glass slides. At particular intervals, the remaining concentration of Aza-A was analyzed by HPLC. Using first-order kinetic equation, the dissipation half-life values （DT^0） for the degradation of Aza-A under ultraviolet radiation were obtained. It indicated that the addition of ferulic acid, gallic acid, and rutin provided moderate degree of photostabilization of Aza-A and that addition of aloin provided the best photostabilization of Aza-A, among these UV absorbers studied. Photostabilization of Aza-A by different UV light absorbers appears to be due to the competitive energy absorption of UV photons by the absorbers molecules. The dissipation half-life values of Aza-A after irradiation under ultraviolet light suggested that the addition of aloin （in 1 ： 1 mol ratio） can provide better photostabilization of azadirachtin molecule.

关 键 词：ultraviolet light PHOTOSTABILIZATION Aza-A BIOINSECTICIDE 

分 类 号：S435[农业科学—农业昆虫与害虫防治]