C_(60)化学修饰的高分子功能材料研究(上)  

Research on Polymarization and Functional Materialization of C_(60)(I)

作　　者：蔡瑞芳[1] 黄祖恩[1] 陈彧[1] 

机构地区：[1]复旦大学化学系,上海200433

出　　处：《上海化工》1996年第5期1-4,共4页Shanghai Chemical Industry

基　　金：国家自然科学基金;国家科委;上海市科委基金资助项目

摘　　要：本研究选择“C_(60)的高分子化学修饰和功能材料化研究”为主题,采用金属有机化学反应技术,以碳负离子为重要的合成前体物质,在常温常压下较简便高效地合成了可溶性C_(60)化学修饰的高分子衍生物,并应用多种现代物理测试技术系统地研究了材料的结构、物理化学性质及其功能化行为.The combination of the outstanding characteristics of [60]fullerene with the properties of other materials like polymers is very challenging. It is reasonable to predicte that the polymerization and materialization of fullerenes will be brilliant and be put into use in the fields, of materials and life science. The contents of this paper include four chapters:1. Photoconductivity and structural characterization of Ceo chemically modified organic polymers; 2. The first electrochemical intercalation of lithium into fullerenated poly(N -vinylcarbazole);3. Synthesis and characterization of soluble C60Chemically modified polystyrene and polystyrene derivatives; 4. Synthesis,Characterization and pyrolytic modification of the soluble and starlike C60(CH3)x(PAN)x copolymers.

关 键 词：高分子化学修饰 功能材料 碳60 高分子材料 

分 类 号：TQ127.1[化学工程—无机化工] TQ324