Mass Spectral Fragmentation of (S,S)-N,N′-Bis [1-(hydroxymethyl)alkyl]anthracene/Naphthalene-1,8-dicarboxamides under Electron Impact Ionization Conditions  

作　　者：JIAO Peng ZHANG Qi-han XU Jia-xi 

机构地区：[1]Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

出　　处：《Chemical Research in Chinese Universities》2006年第6期756-759,共4页高等学校化学研究（英文版）

基　　金：Supported in part by the National Natural Science Foundation of China(No. 20472005).

摘　　要：The mass spectrometric fragmentation of （ S, S） -N, N＇-bis [ 1- （hydroxymethyl） alkyl] anthracene/naphthalene-1, 8-dicarboxamides was investigated with the aid of mass-analyzed ion kinetic energy spectrometry and the elemental compositions of important fragment ions were determined by accurate mass measurement under electron impact ionization conditions. All the compounds could eliminate formaldehyde. The [ M-CH2O] ions could also eliminate imine, aziridine, aziridinone, 2-amonoalkan-1-ol, water, and other fragments. Several cyclizations were observed under electron impact ionization.The mass spectrometric fragmentation of （ S, S） -N, N＇-bis [ 1- （hydroxymethyl） alkyl] anthracene/naphthalene-1, 8-dicarboxamides was investigated with the aid of mass-analyzed ion kinetic energy spectrometry and the elemental compositions of important fragment ions were determined by accurate mass measurement under electron impact ionization conditions. All the compounds could eliminate formaldehyde. The [ M-CH2O] ions could also eliminate imine, aziridine, aziridinone, 2-amonoalkan-1-ol, water, and other fragments. Several cyclizations were observed under electron impact ionization.

关 键 词：Biscarboxamide EI-MS FRAGMENTATION CYCLIZATION 

分 类 号：O625.15[理学—有机化学]