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作 者:张慧慧[1] 郭利伟[1] 邵惠丽[1] 胡学超[1]
机构地区:[1]东华大学材料学院纤维材料改性国家重点实验室,上海200051
出 处:《合成纤维工业》2006年第6期1-3,共3页China Synthetic Fiber Industry
基 金:国家自然科学基金资助项目(20074005);上海市优秀学科带头人计划项目(05XD14025);上海市重点学科建设项目
摘 要:研究了纳米炭黑在Lyocell纺丝溶液中的分散性,制备不同含量纳米炭黑填充的Lyocell纤维,分析了纤维的结构与性能。结果表明:纳米炭黑在Lyocell纺丝溶液中具有良好的分散性;所得的纤维仍然具有纤维素Ⅱ晶型的结构,同时还保留了纳米炭黑的特征衍射峰;填充了纳米炭黑的纤维力学性能略有降低,但热稳定性不变;SEM结果表明纳米炭黑填充的Lyocell纤维表面光滑且截面为圆形,结构更加致密。The dispersity of nano-carbon black in Lyocell spinning solution was studied. The Lyocell fibers filled with different amounts of nano-carbon black were prepared. The structure and properties of the obtained fiber were analyzed. The results showed that the nano-carbon black can be dispersed very well in Lyocell spinning solution. The obtained fibers had cellulose Ⅱ crystal structure and kept the characteristic peak of carbon black at the same time. The mechanical properties of nano-carbon black filled Lyocell fiber decreased slightly but the heat stability remained unchanged. The SEM results showed that the nano-carbon black filled Lyocell fiber had a smooth surface and circular cross section with a compacter structure.
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