含铋(Ⅲ)配合物的合成及铋的配位性质  

Synthesis of Bismuth(Ⅲ) Complexes and Coordination Chemistry of Bismuth(Ⅲ)

作　　者：蒋琪英[1] 沈娟[1] 钟国清[1] 

机构地区：[1]西南科技大学化学系,绵阳621010

出　　处：《化学进展》2006年第12期1634-1645,共12页Progress in Chemistry

基　　金：西南科技大学人才引进专项基金(No.ZK043129)和校内基金(No.ZK053012)资助

摘　　要：由于金属铋的绿色安全性,其配合物的应用领域不断扩大。因此,从分子水平探索配合物结构具有十分重要的意义。本文主要根据有机配体的不同,对三价铋离子配合物的合成及相应的结构进行分类概述,并针对固态铋配合物,对铋(Ⅲ)离子在各配合物中所处的配位环境以及与配体的配位方式等进行了综述。Because of safety, the use of bismuth complexes has been exploring increasingly. It is important to study molecular structures of bismuth complexes based on molecular level, which can provide basic data for exploitation and applicability. In this paper, according to organic ligands including polyaminoearboxylates, hydroxyearbolates, alcohols and so on, coordinative environments, patterns of synthesis and structures of complexes as well as other properties about bismuth complexes in solid state are summarized.

关 键 词：铋(Ⅲ)配合物 配位化学 结构 合成 

分 类 号：O641.4[理学—物理化学] O614.53[理学—化学]