不同原料基活性碳纤维的结构及吸附特征研究  

STUDY ON THE STRUCTURE AND ADSORPTION CHARACTERISTICS OF ACTIVATED CARBON FIBERS FROM DIFFERENT PRECURSOR FIBERS

作　　者：岳中仁[1] 陆耘[1] 符若文[1] 曾汉民[1] 

机构地区：[1]中山大学材料科学研究所

出　　处：《合成纤维工业》1996年第6期11-15,共5页China Synthetic Fiber Industry

基　　金：国家自然科学基金;中山大学科学基金

摘　　要：采用Ｘ－射线衍射，ＳＥＭ和ＢＥＴ比表面分析仪，探讨了不同原料（聚丙烯腈，聚乙烯醇，粘胶，天然纤维和碳纤维）基活性碳纤维的结构和吸附特征。实验表明，所制备的活性碳纤维都具有大致相同的乱层石墨结构，其微晶参数ＬＣ，Ｌａ和ｄ值分别为１．０－１．２，３．９－５．０，０．３８－０．４０ｎｍ，微晶尺寸微小，活性碳纤维（ＡＣＦ）的比表面积越大。ＡＣＦａ的表面形态都不相同且基本保持着原料纤维的形态。The structure and adsorption characteristic of ACFs from different precursor fibers,such as polyacrylonitrile fiber, polyvinyl alcohol fiber,cellulose fiber, nature fiber (sisal) and pitch- based carbon fiber was investigated by means of X- ray diffraction,SEM and BET measuremerits.It was found that the ACFs prepared at the same carbonization and activation conditions had roughly the same turbostratic structure.The apparent parameters of crystallite size,L_c,L_a and d_(002)are 1.0～1.2,3.9～5.0 and 0.38～0.4nm respectively. The larger the crystallite size,the less the specific surface area of ACF was.The surface morphology of five kinds of ACFs was different and evolved from the morphology of precursor fibers. The adsorption amount of benzene onto ACFs was in direct proportion to the specific surface area of ACFs.But no relationship between adsorption amount of Ag￣+ and specific surface area was found. The morphology of Ag particles reduced was affected by the surface morphology of ACFs.The diameter of Ag particle reduced on NACF and AACF is less than 300nm.

关 键 词：活性碳纤维 结构 吸附 碳纤维 

分 类 号：TQ342.86[化学工程—化纤工业] TQ342.742