苯胺在聚丙烯酰胺水、乙二醇溶液中的聚合研究  

Studies on polymerization of aniline in PAM glycol and PAM water solution

作　　者：原玲[1] 李伟[1] 房金辉[2] 黄珂琤[3] 罗云清[1] 龚剑[1] 瞿伦玉[1] 

机构地区：[1]东北师范大学多酸科学教育部重点实验室 [2]柳河县第七中学,吉林柳河135312 [3]长春工业大学,吉林长春130012

出　　处：《分子科学学报》2006年第6期408-411,共4页Journal of Molecular Science

基　　金：教育部留学基金资助项目;吉林省自然科学基金资助项目(20030505-4)

摘　　要：以聚丙烯酰胺为反应基质,分别在聚丙烯酰胺的水、乙二醇溶液中制备了掺杂态导电聚苯胺.探索了合成可溶性导电聚苯胺的最佳条件.采用红外、紫外可见光谱、X射线粉末衍射等手段对产品进行了表征.实验结果表明,在保持聚苯胺电导率基本不变的情况下,采用在聚丙烯酰胺的乙二醇溶液中制备的聚苯胺比水溶液中制备的聚苯胺有较好的溶解率.PANI doped with H4 SiW12O40 was obtained in the PAM aqueous solution and glycol solution, respectively. The PANI was characterized by IR, UV-Vis spectra and XRD patterns. The effect of the ratio of HPA, oxidant, aniline,the temperature of the reaction system on the conductivity, and solubility of the PANI was investigated, respectively. The results showed that the soluble ratio of PANI synthesized in glycol was better than in water Cunder similar conductivity.

关 键 词：聚苯胺 高聚物 水溶性 

分 类 号：O612[理学—无机化学]