稀土-4′,4′-联吡啶-2-羟基-3-萘甲酸固体配合物的合成与表征  

The Synthesis and Characterization of Rare-earth-2-hydroxyl-3-naphthlinate-4,4′-Bipyridine Solid Complexes

作　　者：邓玉恒[1] 王少亭[1] 张帆[1] 

机构地区：[1]首都师范大学化学系,北京100037

出　　处：《首都师范大学学报（自然科学版）》2006年第6期38-39,42,共3页Journal of Capital Normal University：Natural Science Edition

基　　金：北京市科技新星计划(H013610050112);北京市教委项目(2002KJ094)

摘　　要：以95%的乙醇为溶剂合成了4,4′-联吡啶(bipy)、2-羟基-3-萘甲酸(HL)与稀土(RE=La,Nd,Sm,Tb)的三元固体配合物.元素分析确定了它们的化学组成为REL3bipy.nH2O(n=2,3).通过摩尔电导、红外光谱、紫外光谱、热分析,对其性质进行了研究.The ternary solid rare-earth （ RE = La, Nd, Sm, Tb） complexes with 2-hydroxyl-3-naphthlinic acid （HL） and, 4,4＇- Bipyridine （bipy） were synthesized. Their compositions were determined to be REL3＂ Bipy-nH2O （n = 2,3） by the element analysis. The properties of the compounds were studied tentatively by molar conductivity, infrared and ultraviolet absorption spectra and DTA-TGA relatively.

关 键 词：4 4'-联吡啶 2-羟基-3-萘甲酸 稀土配合物 性质表征 

分 类 号：O614.33[理学—无机化学]