Vibrational Spectra of Nonrigid Molecule HCP in an Algebraic Model  

用代数模型研究非刚性HCP分子的振动谱(英文)

作　　者：侯喜文[1] 乔安钦[2] 成传明[2] 

机构地区：[1]华中师范大学物理系,武汉430079 [2]郧阳师范高等专科学校物理系,十堰442700

出　　处：《Chinese Journal of Chemical Physics》2006年第6期478-480,共3页化学物理学报（英文）

摘　　要：An algebraic Harniltonian for the two coupled nonlinear vibrations of highly excited nonrigid molecule HCP was presented. The Hamiltonian reduces to the conventional one in a limit which was expressed in terms of harmonic oscillator operators. It showed that the algebraic model can better reproduce the data than the conventional model by fitting the observed data of HCP.

关 键 词：Vibrational energy levels Algebraic methods Fermi resonances 

分 类 号：O641.1[理学—物理化学]