吡啶-2-羧酸铜的合成及在光促进溴代烃羰基化反应中催化性能研究  

Study of the synthesis of pyridine-2-carboxylate and its catalytic activity on photo-promoted carbonylation of alkyl bromide

作　　者：周广运[1] 尹静梅[1] 贾颖萍[1] 孙丽[1] 崔颖娜[1] 吴智峰[1] 

机构地区：[1]大连大学环境与化学工程学院,辽宁大连116622

出　　处：《大连大学学报》2006年第6期20-22,共3页Journal of Dalian University

基　　金：国家自然科学基金资助项目(20372012);辽宁省自然科学基金资助项目(20032099)

摘　　要：本文合成了Cu(P ic)2(吡啶-2-羧酸铜),用红外光谱进行表征;研究了光促进下,以Cu(P ic)2为催化剂,1-溴辛烷、溴代十二烷、溴代环己烷为底物与CO的羰基化反应,结果表明,Cu(P ic)2对光促进溴代烃的羰基化反应具有良好的催化作用.Cu（Pic） 2 （copper pyfidine-2-carboxylate） was synthesized, and characterized by IR spectrum. The photo-promoted carbonylation of 1-bromooctane, 1-bromododecane, bromocyelohexane with CO catalyzed by Cu（Pic） 2 was carried out. The studied results showed that Cu（ Pic）2 had a good catalytic activity on the photo -promoted earhonylation of alkyl bromide.

关 键 词：Cu(Pic)2 溴代烃 光促进羰基化反应 

分 类 号：O627.12[理学—有机化学]