反相高效液相色谱法测定离子液体及其中的高沸点有机物  

Determination of Ionic Liquids and High B P Organic Compounds by Reversed-phase HPLC

作　　者：姜晓辉[1] 孙学文[1] 赵锁奇[1] 浮东宝[1] 

机构地区：[1]中国石油大学重质油国家重点实验室,北京102249

出　　处：《分析测试技术与仪器》2006年第4期195-198,共4页Analysis and Testing Technology and Instruments

基　　金：国家自然科学基金项目(No.20276038)

摘　　要：建立了反相键合相液相色谱分析离子液体咪唑类离子液体[bmim]PF6[、bmim]BF4、吡啶类离子液体[bupy]BF4的纯度及其中高沸点有机物的方法.以缓冲溶液控制流动相pH值,显著改善了峰形.保留时间定性,外标法定量.The reversed--phase high performance liquid chromatographic method for analysis of ionic liquids [bmim] BF4.[bmim] PF6, [bupy] BF4 ＆ high boiling point organics naphthalene, phenanthrene, diphenyl.DBT.Diphenyldisulfide in them. Peak shape was improved by adjusting pH of mobile phase with buffer solutiom. The nature is qualitatively measured by retentive time, and quantitative analysis is carried out by external standard. The series of methods is significant to determine the solubility of high B. P.organics in ionic liquids.

关 键 词：离子液体 高沸点有机物 高效液相色谱法 

分 类 号：O657.32[理学—分析化学]