MCM-48固载手性salen Mn(III)催化苯乙烯环氧化反应  

Epoxidation of Styrene by Mn(III) Salen Complex Immobilized on MCM-48

作　　者：于凯[1] 王圣杰[1] 楼兰兰[1] 王志龙[1] 丁飞[1] 刘双喜[1] 

机构地区：[1]南开大学化学学院新催化材料科学研究所,天津300071

出　　处：《分子催化》2006年第6期591-593,共3页Journal of Molecular Catalysis(China)

基　　金：国家自然科学基金(29973016和20233030);南开大学-天津大学联合研究院教育部南开大学天津大学科技合作基金项目

摘　　要：Salen Mn(III)/MCM-48 catalyst was prepared and characterized by FT-IR,XRD,UV-Vis,and GC.The catalyst was evaluated by the epoxidation of styrene;remarkable activity and enantioselectivity were received.Salen Mn（Ⅲ）/MCM-48 catalyst was prepared and characterized by FT-IR, XRD, UV-Vis, and GC. The catalyst was evaluated by the epoxidation of styrene; remarkable activity and enantioselectivity were received.

关 键 词：手性SALEN Mn(Ⅲ) MCM-48 苯乙烯 不对称环氧化 

分 类 号：O643.32[理学—物理化学]