高效液相色谱法测定卷烟主流烟气中的低分子醛酮类化合物  

DETERMINATION OF LOW-MOLECULAR-MASS CARBONYL COMPOUNDS OF MAINSTREAM SMOKE BY HPLC

作　　者：徐济仓[1] 侯英[1] 杨式华[1] 周萍萍 吴永宁 

机构地区：[1]云南烟草科学研究院,昆明650106 [2]中国疾病预防及控制中心营养与食品安全所,北京100050

出　　处：《环境化学》2006年第6期678-682,共5页Environmental Chemistry

基　　金：国家烟草专卖局课题110200201021资助

摘　　要：通过对吸烟机接口的改装,应用酸化的2,4二-硝基苯肼的乙腈溶液作为吸收液,对主流烟气中的甲醛、乙醛、丙酮、丙醛、丙烯醛、丁醛、丁烯醛、丁酮进行衍生化,形成相应的苯腙,采用紫外检测器在波长为360nm处进行检测,方法的最小检测限在0.54—1.65ng.μl-1之间,样品中被检测物的RSD值在6.22%—12.34%(n=6)之间.The joint of smoking machine was redesigned, and 2,4-dinitrophenylhydrazine in acidic acetonitrile solution was used to absorb formaldehyde, acetaldehyde, acrolein, acetone, propionaldehyde, crotonaldehyde, methyl ethyl ketone and butyraldehyde in mainstream smoke, and formed 2,4-dinitrophenylhydrazones, which were determined by high performance of liquid chromatography using UV detector at 360nm. The lowest detection levels of method were 0. 54-1. 65ng·μl^-1 , and RSD were 6.22%-12. 34% （n =6）. Some brands of cigarretts were determined and the results were content.

关 键 词：低分子醛酮类化合物 高效液相色谱法 2 4-二硝基苯肼 主流烟气 

分 类 号：TS411[农业科学—烟草工业]