金刚烷的结构、溶解性及热力学性质  

Structure Analysis,Solubility and Thermodynamics Properties of Adamantane

作　　者：刘卅[1] 郭建维[2] 

机构地区：[1]华南理工大学材料科学与工程学院,广州510640 [2]广东工业大学轻工化工学院,广州510006

出　　处：《含能材料》2006年第6期485-490,共6页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金(20026005);广东省科技计划项目(2005B10301008)

摘　　要：介绍了表征金刚烷分子和晶体结构的XRD、FT-IR、MS、NMR、EMS、DMS、RAMAN、DSC等多种谱图特征,分析了金刚烷晶体随温度、压力变化而产生晶相转变的特征,归纳了金刚烷的热力学性质及其在不同溶剂、不同温度下的溶解度。例举了多硝基金刚烷和氮杂多硝基金刚烷在高能量密度(HEDM)分子设计中的最新研究状况。The characterizing methods of molecular structure and crystal phase of adamantane including XRD, FT-IR, MS, NMR, EMS,DMS,BAMAN, DSC, etc were introduced in order to foretell adamantane chemistry and its application prospect in energetic materials. The phase transition behavior of adamantane at different temperature or pressure conditions was discussed as well. Finally,the thermodynamic properties and solubility of adamantane in various of organic solvents were reviewed respectively. The latest research progress of polynitroadamantanes and polynitroazaadamantanes in HEDM molecular design were also illustrated.

关 键 词：物理化学 金刚烷 结构 溶解度 热力学 

分 类 号：O611.3[理学—无机化学]