Convenient synthesis of β-allenic α-difluoromethylenephosphonic acid monoesters:Potential synthons for cyclic phosphate mimics  

作　　者：Yun Lin Jin Tao Liu 

机构地区：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China [2]College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097, China

出　　处：《Chinese Chemical Letters》2007年第1期33-36,共4页中国化学快报（英文版）

基　　金：We thank the National Natural Science Foundation of China for financial support(No.20572124).

摘　　要：β-Allenic α-difluoromethylenephosphonic acid monoesters were prepared under mild conditions for the first time by hydrolyzing the corresponding diethyl phosphonates in aqueous sodium hydroxide solution.β-Allenic α-difluoromethylenephosphonic acid monoesters were prepared under mild conditions for the first time by hydrolyzing the corresponding diethyl phosphonates in aqueous sodium hydroxide solution.

关 键 词：β-Allenic α-difluoromethylenephosphonic acid monoester Hydrolysis Phosphate mimic 

分 类 号：O623.624.2[理学—有机化学]