C_5馏份的综合利用──超强酸合成金刚烷  

COMPREHENSIVE UTILIZATION OF C_5-FRACTION-SYNTHESIS OF ADAMANTANE BY ULTRASTRONY ACID CATALYST

作　　者：蒋端六[1] 蒋持衡[1] 

机构地区：[1]无锡教育学院化学系,中国科学院上海有机化学研究所

出　　处：《江苏化工》1996年第6期25-26,29,共3页Jiangsu Chemical Industry

摘　　要：采用新的超强酸──全氟磺酸树脂（Ｈ_０＞１１）催化体系合成金刚烷，使反应朝一个方向进行，无副产物生成，同时具有高的催化活性和高的转化率。是综合利用Ｃ_５馏份的新途径。Adamantane was synthesized by using a new ultrastrong acid-porfluorosulfonic resin ( H_O > 11) as the catalytic system. The reaction was singly directional without side products. The catalytic system had high calalytic activity and conversion yield. It was a new method for comprehensive utilization of C_5-fraction.

关 键 词：超强酸 金刚烷 碳5 三环癸烷 癸烷 

分 类 号：TQ221.19[化学工程—有机化工]