Lewis Base-Catalyzed Formation of α-Trifluoromethyl Alcohol from CF3SiMe3 and Carbonyl-Containing Compounds  

作　　者：祝诗发 庞婉 邢春晖 朱仕正 

机构地区：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

出　　处：《Chinese Journal of Chemistry》2007年第2期233-236,共4页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （Nos. 20472106 and 20532040）.

摘　　要：Lewis base could catalyze the formation of a-trifluoromethyl alcohol from CF3SiMe3 and carbonyl-containing compounds. It was found that the α-trifluoromethyl alcohol could also be used to promote the synthesis in basic conditions.Lewis base could catalyze the formation of a-trifluoromethyl alcohol from CF3SiMe3 and carbonyl-containing compounds. It was found that the α-trifluoromethyl alcohol could also be used to promote the synthesis in basic conditions.

关 键 词：atom-economic TRIFLUOROMETHYL organic synthesis 

分 类 号：O623.4[理学—有机化学]