流化床与固定床中甲烷裂解制氢过程的比较  

Comparison of fluidized and fixed bed operations for hydrogen production from methane decomposition

作　　者：刘少文[1] 李永丹[1] 

机构地区：[1]天津市应用催化科学与工程重点实验室天津大学化工学院,天津300072

出　　处：《化工学报》2007年第1期102-107,共6页CIESC Journal

基　　金：国家自然科学基金项目(20425619)~~

摘　　要：The effect of reaction modes,i.e.fluidized bed and fixed bed operations,on catalyst life for hydrogen production from methane decomposition was investigated over a 75Ni15Cu10Al catalyst and a 2Co1Al catalyst.Pure methane was used as the feed.The results showed that the apparent reaction rate in the fluidized bed was much higher than that in the fixed bed,indicating that in the fixed bed the reaction was transport-controlled.The carbon formed was characterized with TEM technique,and the results showed that the size of metal particles increased with rising reaction temperature,and at the same reaction temperature the size of metal particles on the catalyst in the fixed bed was larger than that on the catalyst in the fluidized bed,signifying that fluidized bed reactor is beneficial to preventing the sintering of active metals.The effect of reaction modes, i. e. fluidized bed and fixed bed operations, on catalyst life for hydrogen production from methane decomposition was investigated over a 75NilSCu10Al catalyst and a 2ColAl catalyst. Pure methane was used as the feed. The results showed that the apparent reaction rate in the fluidized bed was much higher than that in the fixed bed, indicating that in the fixed bed the reaction was transport-controlled. The carbon formed was characterized with TEM technique, and the results showed that the size of metal particles increased with rising reaction temperature, and at the same reaction temperature the size of metal particles on the catalyst in the fixed bed was larger than that on the catalyst in the fluidized bed, signifying that fluidized bed reactor is beneficial to preventing the sintering of active metals.

关 键 词：甲烷裂解 制氢 反应器 流态化 碳生长 

分 类 号：TQ032.4[化学工程]