PVDF/PANI—TSA复合纤维膜的电纺制备及电性能  

Electrospinning and Characterization of Poly(vinylidene Fiuoride)/Polyaniline Doped with P-toluene Sulphonic Acid Composite Nanofibrous Membrane

作　　者：孙涛[1] 周明阳[1] 李新松[1] 

机构地区：[1]东南大学化学化工学院生物材料和药物释放实验室,江苏南京210096

出　　处：《化工时刊》2007年第1期9-11,24,共4页Chemical Industry Times

基　　金：国家自然科学基金(NSFC50573011;50673019)

摘　　要：利用电纺技术制备了对甲苯磺酸掺杂的聚苯胺(PANI-TSA)/聚偏氟乙烯(PVDF)复合电纺纤维膜。并用电导率仪,SEM,静电电位计,电化学工作站,力学试验机等进行表征。研究表明PANI-TSA的加入增强了纺前溶液的电导率,显著提高了膜的电导率和抗静电性能。同时由于部分PANI-TSA没有溶解,以颗粒状存在纤维中,纤维表面因此变得粗糙,拉伸强度略有降低。Poly（vinylidene fluoride） （PVDF） was blended with Polyaniline which doped with p- toluene sulphonic acid （PANI- TSA）, and co- electrospun into nanofibrous membranes.The composite membranes were characterized using scanning electron microscopy （SEM）,electrical conductivity measurement, mechanical tensile testing.The data indicate that with increasing the amount of PANI - TSA （from 0 to 0.05 m/m） ,it became hard to spin, and the electrical conductivity was increased from 0.225 mS/cm to 1.83 ms/cm,and melectrostatic potential reduced from 6 kV to 0.8 kV.So,the PANI was responsible for the high electrical conductivity of the blend. Because of the existence of PANI granules, the tensile strength and elongation at break decreases.

关 键 词：聚偏氟乙烯 聚苯胺 电纺 膜 

分 类 号：TQ340.6[化学工程—化纤工业]