含锡催化剂在Baeyer-Villiger氧化反应中的应用进展  

Progress in Application of Tin-Containing Catalysts to Baeyer-Villiger Oxidation

作　　者：黄靓[1] 李静霞[1] 戴维林[1] 曹勇[1] 范康年[1] 

机构地区：[1]复旦大学化学系上海市分子催化与创新材料重点实验室,上海200433

出　　处：《石油化工》2007年第2期200-204,共5页Petrochemical Technology

基　　金：国家自然科学基金项目(20407006;20573024);上海市科委基础研究重点项目(06JC14004)

摘　　要：综述了近年来含锡催化剂在Baeyer-Villiger反应(酮转化为相应的酯或内酯的反应)中的应用研究进展,分别介绍了Sn-β沸石、Sn-MCM-41、水滑石负载锡、坡缕石负载锡等非均相催化剂及锡的全氟化辛烷磺酰胺配合物、苯胺和苯甲醇取代的有机锡配合物等均相催化剂。由于非均相催化剂能回收重复利用,着重介绍了各种非均相催化剂的优缺点及催化作用机理。其中,Sn-β沸石由于具有较多的小孔,有利于Sn的嵌入,从而有效提高了反应的转化率,而Sn-MCM-41、水滑石负载锡、坡缕石负载锡等催化剂虽合成方法简单,但其活性均低于Sn-β沸石催化剂。Recent development in research of tin - containing catalysts used in Baeyer - Villiger oxidation was reviewed. The heterogeneous and homogeneous catalysts, namely Sn -β zeolite, Sn - MCM -41, Sn - hydrotalcite, Sn - palygorskite, Sn - perfluorooctanesulfonyl amide complex, aniline - Sn and benzyl alcohol - Sn, were introduced. Catalytic mechanisms of some catalysts for the oxidation were discussed. The heterogeneous catalysts can be reused. Because Sn can be easily introduced into micropores on Sn -β zeolite support, activity of catalyst in the reaction is high. Activity of other heterogeneous catalysts are lower than that of Sn -β zeolite, although their preparation processes are much more simple.

关 键 词：Baeyer-Villiger氧化反应 含锡催化剂 酮 酯 内酯 

分 类 号：TQ032.42[化学工程]