六氢吡啶团簇的研究  

The Study of the 6-H Pyridine Clusters

作　　者：陈文武[1] 高毅勤[1] 吴国胜[1] 杨达林[1] 盛六四[2] 武国华[2] 叶为全[2] 张允武[2] 

机构地区：[1]中国科学院化学研究所分子反应动力学国家重点实验室,北京100080 [2]中国科学技术大学国家同步辐射实验室,合肥230027

出　　处：《物理化学学报》1996年第12期1067-1070,共4页Acta Physico-Chimica Sinica

基　　金：国家自然科学基金;国家同步辐射实验室开放基金

摘　　要：The 6H-pyridine clusters have been studied by the TOF mass spectrometry,the VUV from synchrotron rediation and the molecular beam technique three-type clusters are observed in the VUV photoionization mass spectroscopy: Pn+(n=2-5,P stands for6H-pyridine molecule), PnH+ (n=2-4) and Pn (H2O)m+(n=4,5, m=1;n=6, m=1,2). ThePnH+ clusters may have the chain structure,the Pn+ and Pn(H2O)m+ clusters may havethe cyclic structures, all of these are formed by the hydrogen-bond.The 6H-pyridine clusters have been studied by the TOF mass spectrometry,the VUV from synchrotron rediation and the molecular beam technique three-type clusters are observed in the VUV photoionization mass spectroscopy: Pn+(n=2-5,P stands for6H-pyridine molecule), PnH+ (n=2-4) and Pn (H2O)m+(n=4,5, m=1;n=6, m=1,2). ThePnH+ clusters may have the chain structure,the Pn+ and Pn(H2O)m+ clusters may havethe cyclic structures, all of these are formed by the hydrogen-bond.

关 键 词：六氢吡啶 分子团簇 氢键 环状结构 链状结构 

分 类 号：O626.321[理学—有机化学]