键合于聚苯乙烯的铁（Ⅲ）卟啉的合成、表征及其模拟细胞色素P450催化环己烷的羟化作用  

THE SYNTHESIS OF POLYSTYRENE-BONDED CHLOROPORPHYRINATOIRON(Ⅲ) AND AS THE MODEL OF CYTOCHROME P450 TO CATALYZE HYDROXYLATION OF CYCLOHEXANE

作　　者：刘展良[1] 黄锦汪 计亮年 劳彩玲[1] 

机构地区：[1]中山大学化学系,中国科学院兰州化学物理研究所OSSO国家重点实验室,中山大学测试中心

出　　处：《离子交换与吸附》1996年第3期217-222,共6页Ion Exchange and Adsorption

基　　金：国家自然科学基金;广东省自然科学基金

摘　　要：三种铁（Ⅲ）卟啉配合物被直接固载于聚苯乙烯。ＵＶ—ｖｉｓ，ＩＲ和ＥＰＲ研究表明，铁（Ⅲ）卟啉是通过醚键共价键合于聚苯乙烯，中心离子铁（Ⅲ）处于高自旋态（Ｓ＝５／２）。研究了它们作为细胞色素Ｐ４５０模拟体，在以Ｏ２为氧源时对环己烷羧化的催化作用，对影响催化活性的因素进行了讨论。Three kinds of polystyrene- bonded chloroporphyrinatoirons were synthesized by a new method and characterized by UV-vis, IR and EPR spectra. The results showed that iron(Ⅲ) porphyrins were covalently bonded to polystyrene via ether linkage. These polystyrene-bonded chloroporphyrinatoiron(Ⅲ) as model systems of cytochrome P - 450 are effective for the hydroxylation of cyclohexane with molecular oxygen under mild conditions and their catalytic activities are higher than those of correspondent nonsupported iron (Ⅲ ) porphyrins. Factors affecting catalytic activities are discussed.

关 键 词：聚苯乙烯 铁卟啉 环己烷 羟化 催化 

分 类 号：O614.811[理学—无机化学] O643.36[理学—化学]