超声波辅助杂多酸催化环己醇氧化合成己二酸  

Oxidation of Cyclohexanol to Adipic Acid Catalyzed by Heteropoly Acid with Aid of Ultrasound

作　　者：隆金桥[1] 凌绍明[1] 

机构地区：[1]广西右江民族师范高等专科学校化学与生命科学系,广西百色533000

出　　处：《化学世界》2006年第9期558-560,共3页Chemical World

摘　　要：在超声波作用下，以磷钨酸为催化剂，用过氧化氢氧化环己醇的方法合成了己二酸。探讨了物料配比、催化剂用量、反应温度、反应时间对己二酸产率的影响。在环己醇用量10．5mL，30％过氧化氢溶液用量60mL，催化剂用量0．5mmol，反应温度75℃，反应时间8h，己二酸产率达82．1％。最佳条件下的产率比常规方法的产率（60％-70％）高出12％。实验结果表明，这是一种合成己二酸的切实可行的绿色化学工艺。Adipie acid was synthesized under ultrasonic irradiation using cyclohexanol and hydrogen peroxide as raw materials and phosphotungstic acid as a catalyst. The effect of materials ratio, catalyst amount, reaction temperature and time on the yield of adipic acid was studied. The yield of adipic acid reached 82.1% when the amount of cyclohexanol, 30% hydrogen peroxide and catalyst were 10.5 mL, 60 mL and 0.5 mmol, respectively, the reaction temperature was 75 ℃ and the reaction time was 8 h. The yield of this method was higher than in ordinary method（60% - 70% ）. This is a feasible and green chemical process to synthesize adipic acid.

关 键 词：超声波 己二酸 磷钨酸 

分 类 号：O643[理学—物理化学]