Hydrothermal Synthesis and Crystal Structure of Manganese(Ⅱ) Coordination Polymer Assembled by 4-Sulfophthalate and 4,4′-Bipyridine  

作　　者：WANG Qing-wei LI Xiu-mei GAO Guang gang 

机构地区：[1]Department of Chemistry, Jilin Normal University, Siping 136000, P. R. China [2]Department of Chemistry, Tonghua Teachers College, Tonghua 134002, P.R. China

出　　处：《Chemical Research in Chinese Universities》2007年第1期105-108,共4页高等学校化学研究（英文版）

基　　金：Supported by the Education Office of Jilin Province of China(No 0047)

摘　　要：The rational design and synthesis of metal-directed supramolecular framework compounds have received much attention in coordination chemistry because of their potential applications in catalysis, molecular selection, nonlinear optics, ion exchange, and microelectronics. Many high-dimensional coordination complexes have been designed and prepared through molecular self-assembly processes. The open metal organic framework can be produced via two kinds of interactions, i. e. , coordinate covalent bonds and weaker intermolecular forces. For this reason, the most efficient means to synthesize these compounds is to establish possible connections among different units.The rational design and synthesis of metal-directed supramolecular framework compounds have received much attention in coordination chemistry because of their potential applications in catalysis, molecular selection, nonlinear optics, ion exchange, and microelectronics. Many high-dimensional coordination complexes have been designed and prepared through molecular self-assembly processes. The open metal organic framework can be produced via two kinds of interactions, i. e. , coordinate covalent bonds and weaker intermolecular forces. For this reason, the most efficient means to synthesize these compounds is to establish possible connections among different units.

关 键 词：Hydrothermal synthesis Crystal structure Supramoleeular network Mixed ligand 

分 类 号：O614.711[理学—无机化学] O641.4[理学—化学]