A Study on the Reaction of 1-（3-Pyridyl）-2,2-di-substituted Ethylenes with 1-Benzyl-1,4-dihydronicotinamide  

作　　者：许华建 刘有成 傅尧 

机构地区：[1]Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China [2]College of Chemistry, Lanzhou University, Lanzhou, Gansu 730000, China

出　　处：《Chinese Journal of Chemistry》2007年第1期95-97,共3页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （No. 20072036） and the Specialized Research Fund for the Doctoral Program of Higher Education of China.

摘　　要：The reaction of a series of 1-（3-pyridyl）-2,2-di-substituted ethylenes with 1-benzyl-1,4-dihydronicotinamide （BNAH） in deaerated acetonitrile produces the corresponding 1-（3-pyridyl）-2,2-di-substituted ethanes in contrast to benzylidenemalononitrile （BM） which does not react with BNAH under the same conditions.The reaction of a series of 1-（3-pyridyl）-2,2-di-substituted ethylenes with 1-benzyl-1,4-dihydronicotinamide （BNAH） in deaerated acetonitrile produces the corresponding 1-（3-pyridyl）-2,2-di-substituted ethanes in contrast to benzylidenemalononitrile （BM） which does not react with BNAH under the same conditions.

关 键 词：1-benzyl-1 4-dihydronicotinamide 1-（3-pyridyl）-2 2-di-substituted ethylene benzylidenemalononitrile concerted hydride transfer 

分 类 号：O625.12[理学—有机化学]