ReCl（CO）5-catalyzed Reactions of Aromatic Compounds with 1,3,5-Trioxane or Aqueous Formaldehyde Affording Diarylmethanes  

作　　者：华瑞茂 何俊义 孙宏滨 

机构地区：[1]Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

出　　处：《Chinese Journal of Chemistry》2007年第1期132-135,共4页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （No. 20573061）.

摘　　要：ReCI（CO）5 catalyzed the dehydration reaction of aromatic compounds with 1,3,5-trioxane or aqueous formaldehyde （37 wt%） under air. The reactions of a variety of aromatic compounds beating electron-donating group（s） with 1,3,5-trioxane afforded the corresponding diarylmethanes in moderate to good yields.ReCI（CO）5 catalyzed the dehydration reaction of aromatic compounds with 1,3,5-trioxane or aqueous formaldehyde （37 wt%） under air. The reactions of a variety of aromatic compounds beating electron-donating group（s） with 1,3,5-trioxane afforded the corresponding diarylmethanes in moderate to good yields.

关 键 词：AROMATIC CATALYSIS DEHYDRATION diarylmethane TRIOXANE 

分 类 号：O625.14[理学—有机化学]