日本关东冬季飘尘酸度及其对酸雨形成的影响  

Acidity of winter SPM in Kando of Japan and its contribution for acid rain formation

作　　者：王玮[1,2] 王文兴[1,2] 陈宗良[1,2] 全浩[1,2] 唐珂 坂本和彦 王青跃[3,4] 

机构地区：[1]中国环境科学研究院 [2]国家环保局中日友好环境保护中心 [3]沈阳市环境科学研究所 [4]日本琦玉大学工学部环境化学工学科

出　　处：《中国环境科学》1996年第6期438-442,共5页China Environmental Science

基　　金：日本国际善邻协会资助

摘　　要：利用微量酸碱滴定方法测定日本关东地区冬季高浓度飘尘的酸度，估算了飘尘对酸性降水的缓冲能力，并对飘尘水溶性离子组成进行了分析。结果发现：该地区飘尘的酸性很强，Ｈ＋浓度在２４ｎｅｑ／ｍ３以上，是我国北方城市飘尘的几千倍，这表示该地区大气环境已严重酸化，可能是该地区酸雨形成的主要原因；飘尘的水溶性离子组成与我国飘尘截然不同，飘尘中Ｃｌ－浓度很高，ＳＯ４２－、ＮＯ３－的浓度也较高，说明飘尘主要来自人为源，ＮＨ４＋浓度则占全部阳离子８０％以上，飘尘的这种组成也是非常特殊的。The acidity of aerosols collected in Kando plain in winter was measured by micro acid base titratim method and the buffering capability of aerosols on acidic rainwater was caculated. We find that the acidify of aerosols in this area is very high, and H + concentration is more than 24neq/m 3, which is several thousand times higher than the one in northern China cities The high acidity of aerosol shows that the atmospheric acidification is very serious and this may be the main reason of the acid rain formation in this area. Results also show that the ionic compositions of rain water in Kando plain are very different from that in China, Cl - concentration is very high, the ones of SO 4 2- ,NO - 3are also quite high, This shows that artificial sources are the main source of SPM. NH + 4 concentration accounts for more than 80% of tatol cations. This compositions of SPM are very special.

关 键 词：飘尘 酸雨 缓冲能力 酸度 日本 关东 冬季 

分 类 号：X513.02[环境科学与工程—环境工程] X517.02