HATR-FTIR应用于原产地中药材白术的测定方法研究  

Application of HATR-FTIR Spectroscopy to the Analysis of Quality Mensuration of Rhizoma Atractylodes

作　　者：洪庆红[1,2] 程存归[3] 成则丰[3] 李丹婷[3] 

机构地区：[1]金华职业技术学院材料与化工学院 [2]浙江师范大学化学与生命科学学院,浙江金华321004 [3]浙江师范大学化学与生命科学学院

出　　处：《光谱学与光谱分析》2007年第2期283-286,共4页Spectroscopy and Spectral Analysis

基　　金：浙江省自然科学基金项目(301468)资助

摘　　要：采用傅里叶变换红外光谱的各种测定方法测定了植物中药材白术,通过白术木质部及外表皮部的水平衰减全反射傅里叶变换红外光谱(HATR-FTIR)吸收比较,表明了外表皮含有更多的白术内酯及其衍生物等物质。新鲜的白术木质部比干燥白术木质部含有更多的化学物质,这可能是样品干燥后挥发油减少之故。对白术木质部及其伪品的木质部的HATR-FTIR进行二阶导数转换,进行峰位一致率检验,结果差异极显著。The present paper used many kinds of mensuration of FTIR spectroscopy to determine traditional Chinese drugs-Rhizoma Atractylodis Macrocephalae. Comparing the horizontal attenuated total reflection-Fourier transform infrared spectra（HA- TR-FTIR） of xylem and outer layer parts of cuticle indicates that there are more butenolide and its derivatives in outer layer parts of cuticl~ Much more chemical materials could be found in fresh sample than in drying sample, possibly due to the decreased amount of naphtha in the drying sample. The HATR-FTIR of xylem of Rhizoma Atractylodis Macrocephalae and its confusable varieties were transformed into second derivative FTIR to make sure whether the peak location is consistent. As a result, the difference is significant.

关 键 词：水平衰减全反射傅里叶变换红外光谱法(HATR-FTIR) 白术 质量 测定方法 

分 类 号：O657.3[理学—分析化学]