5-(对-羟基苯基)-10,15,20-三苯基卟啉的金属化及性质表征  

Metallization and Characterization of meso-5-(p-hydroxyphenyl)-10,15,20-triphenylporphyrin

作　　者：单凝[1] 郑文琦[1] 法焕宝[1] 王杏乔[1] 

机构地区：[1]吉林大学化学学院,长春130021

出　　处：《吉林大学学报（理学版）》2007年第2期283-287,共5页Journal of Jilin University:Science Edition

基　　金：国家自然科学基金(批准号:20071014)

摘　　要：设计、合成、分离了5-(对羟基苯基)-10,15,20-三苯基卟啉化合物,并合成其金属配合物.通过元素分析,IR,UV-vis和1HNMR等方法确证了这些化合物的结构,给出了卟啉类配体与金属配合物的IR,UV-vis和1HNMR判据,并对它们的热稳定性质进行了研究.Different transition metalloporphyrins （ Mn, Fe, Co, Ni, Cu, Zn） were prepared, purified and they were characterized by means of element analysis, IR, UV-vis and 1^ HNMR. The correlation between the structures of the compounds and their 1^HNMR, IR, UV spectra was discussed and their specific spectra were explained. The thermostabilities of the compounds were studied with the aid of TGA-TDA.

关 键 词：金属卟啉 表征 差热热重 

分 类 号：O614[理学—无机化学]