六(甲氧基乙氧基乙氧基)三聚磷腈的合成与表征  

Synthesis and characterization of hexa(methoxyethoxyethoxy) cyclotriphosphazene

作　　者：殷跃凡[1] 黄荣[2] 李艳梅[1] 毕韵梅[1] 

机构地区：[1]云南师范大学化学化工学院,云南昆明650092 [2]云南大学化学科学与工程学院,云南昆明650031

出　　处：《化学研究与应用》2007年第3期258-260,共3页Chemical Research and Application

基　　金：国家自然科学基金(20364002)资助项目;中国科学院"西部之光"人才培养计划资助项目;云南省自然科学基金(2005B0027M)资助项目

摘　　要：以六氯三聚磷腈和甲氧基乙氧基乙醇为主要原料,合成了全取代的六(甲氧基乙氧基乙氧基)三聚磷腈,并用IR、31P NMR、1HNMR、13C NMR、FABMS等现代谱学技术对其结构进行了表征。经生物活性试验证明,此化合物对腐生线虫Panagrellus redivivus具有一定的毒杀活性。Synthesis, characterization and biological activity of hexa （methoxyethoxyethoxy） cyclotriphosphazene, a new small-molecule phosphazene were described. The reaction of methoxyethoxyethanol with sodium hydride yielded sodium methoxyethoxyethanol. The rifle compound was prepared by nucleophilic substitution reaction of hexachlorecyclotriphosphazene with sodium methoxyethoxy- ethanol. Its structure was characterized by IR、^31P NMR、^1H NMR、^13C NMR and FABMS. The experiment of the nematicidal activitity was carried out. The obtained results showed that the compound was able to kill 32.8% of the Panagrellus redivivus at lmg/mL within 72 hours.

关 键 词：六(甲氧基乙氧基乙氧基)三聚磷腈 甲氧基乙氧基乙醇 合成 

分 类 号：O623.762[理学—有机化学]