Synthesis and Crystal Structure of N-Phenylbis(ferrocenecarboxyl)imide  

作　　者：ZHAO Feng LI Ganga WU Jing-Xia ZHANG Zong-Pei 

机构地区：[1]Department of Chemistry, Zhengzhou University, Henan 450052, China [2]Office of Research Administration, Zhengzhou University, Henan 450052, China

出　　处：《Chinese Journal of Structural Chemistry》2007年第3期291-294,共4页结构化学（英文）

基　　金：the National Natural Science Foundation of China (No. 20501017)

摘　　要：The ferrocenyl compound, N-phenylbis（ferrocenecarboxyl）imide （C28H23NO2Fe2, Mr = 517.17）, was synthesized and structurally characterized by means of X-ray single-crystal diffraction. It crystallizes in monoclinic, space group C2/c with a = 21.374（14）, b = 10.430（7）, c = 10.741（7） A, β= 114.184（8）°, V= 2184（2） A^3, Z= 4, Dc = 1.573 g/cm^3, F（000） = 1064, μ（MoKα） = 1.355 mm ^-1, T= 291（2） K, the final R = 0.0548 and wR = 0.1437 for 1524 observed reflections with 1 〉 2σ（I）. In this compound, the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative.The ferrocenyl compound, N-phenylbis（ferrocenecarboxyl）imide （C28H23NO2Fe2, Mr = 517.17）, was synthesized and structurally characterized by means of X-ray single-crystal diffraction. It crystallizes in monoclinic, space group C2/c with a = 21.374（14）, b = 10.430（7）, c = 10.741（7） A, β= 114.184（8）°, V= 2184（2） A^3, Z= 4, Dc = 1.573 g/cm^3, F（000） = 1064, μ（MoKα） = 1.355 mm ^-1, T= 291（2） K, the final R = 0.0548 and wR = 0.1437 for 1524 observed reflections with 1 〉 2σ（I）. In this compound, the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative.

关 键 词：N-phenylbis（ferrocenecarboxyl）imide SYNTHESIS crystal structure 

分 类 号：O614.811[理学—无机化学] O625.632[理学—化学]