脱氢枞胺水杨醛Schiff碱及其铜配合物合成条件研究  

Study on Synthesis of Dehydroabietylamine Salicylal Schiff Base and its Copper Complexes

作　　者：李德昌 郑允飞[2] 崔国友[2] 陈文纳[2] 

机构地区：[1]广西化工研究院,广西南宁530001 [2]广西师范学院化学系,广西南宁530001

出　　处：《化工技术与开发》2007年第3期1-3,共3页Technology & Development of Chemical Industry

基　　金：广西科技厅青年基金项目(桂科基0342005-4)

摘　　要：脱氢枞胺与水杨醛反应合成脱氢枞胺水杨醛Schiff碱(Ⅰ),(Ⅰ)与醋酸铜反应合成了脱氢枞胺水杨醛Schiff碱铜配合物(Ⅱ)。通过初步的合成条件探索之后,运用正交实验对合成条件优化,结果(Ⅰ)和(Ⅱ)的产率分别比文献值报道的最高产率高出3%和7%。Dehydroabietylamine salicylal Schiff base （Ⅰ） was synthesized by the reaction of dehydroabietylamine and salicylal. Dehydroabietylamine salicylal Schiff base copper complexes （Ⅱ） was prepared from the reaction of cupric acetate and compound （Ⅰ ） . After the exploration of preliminary synthesis condition, the synthesis conditions were optimized by the orthogonal experiment. The yield of compound （Ⅰ）and （Ⅱ ） were improved 3 % and 7% respectively compared with the maximum yield of the literature value.

关 键 词：脱氢枞胺 水杨醛 SCHIFF碱 铜配合物 合成 

分 类 号：TQ351.471[化学工程]