Reduced Species （HSO2^-, SO2^·-） Promoted One-Pot Efficient Synthesis of Phenyl Alkyl Selenides  

作　　者：汤日元 钟平 林秋莲 

机构地区：[1]School of Chemistry and Material Science, Wenzhou University, Wenzhou, Zhejiang 325027, China

出　　处：《Chinese Journal of Chemistry》2007年第4期558-561,共4页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （No. 20572079）, the Natural Science Foundation of Zhejiang Province （Nos. Y205540 and Y404039） and the Wenzhou University Postgraduate Innovation Foundation （No. YCX0514）.

摘　　要：Reduced species （HSO2^-, SO2^·-） promoted one-pot synthesis of phenyl alkyl selenides has been developed. This synthetic method was achieved by reactions of diphenyl diselenide with alkyl halides at room temperature. It is noteworthy that the reactions were operated under mild reaction conditions, required short time, and got good resuits. A single electron transfer reaction mechanism was proposed for the reaction.Reduced species （HSO2^-, SO2^·-） promoted one-pot synthesis of phenyl alkyl selenides has been developed. This synthetic method was achieved by reactions of diphenyl diselenide with alkyl halides at room temperature. It is noteworthy that the reactions were operated under mild reaction conditions, required short time, and got good resuits. A single electron transfer reaction mechanism was proposed for the reaction.

关 键 词：DISELENIDE SELENIDE RONGALITE sodium dithionite ONE-POT 

分 类 号：O625.322[理学—有机化学]