硼改性酚醛树脂的合成  

Synthesis of Phenolic Resin Modified with Boron

作　　者：霍靓靓[1] 朱靖[1] 尹红娜 赵献增[3] 王冬梅[3] 

机构地区：[1]河南工业大学化学化工学院,郑州450052 [2]河南省商业科学研究所有限责任公司,郑州450002 [3]河南省精细化工重点实验室,郑州450002

出　　处：《河南科学》2007年第2期204-207,共4页Henan Science

基　　金：河南省自然科学基金资助项目(0411020100)

摘　　要：通过在一定条件下,先将苯酚、甲醛制成羟甲基酚,然后改变条件与硼酸共聚,制得具有合成稳定和较好耐热性的硼改性酚醛共聚树脂.探讨催化剂种类、酚醛比、硼酸加入量等对其性能的影响.用红外光谱和热分析手段对该改性树脂的结构和热性能进行了分析表征.Boracic modified penolic resin with boracic acid and hydroxymethyl phenol was manufactured after hydroxymethyl phenol was created with in a special way. The influences which caused by the kinds of the catalyzer, phenol and fornaldehyde proportion, boracic acid addition and etc were discussed. The structure of the resin and its thermo capability were analyzed and characterized by IR and thermoanalysis.

关 键 词：酚醛树脂 硼改性 三元共聚 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]