Transesterification of Ethylene Carbonate with Dimethyl Terephthalate over Various Metal Acetate Catalysts  

作　　者：ZHANG Dan JIA Shu-yong WANG Yue YAO Jie WANG Gong-ying 

机构地区：[1]Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China [2]Graduate School of Chinese Academy of Sciences, Beijing 100039, P. R. China

出　　处：《Chemical Research in Chinese Universities》2007年第2期173-175,共3页高等学校化学研究（英文版）

基　　金：the National High Technology Research and Development Program of China(No 2003AA321010)

摘　　要：The reaction between ethylene carbonate and dimethyl terephthalate was carried out for the simultaneous synthesis of dimethyl carbonate and poly（ethylene terephthalate）, This reaction is an excellent chemical process that is environmentally friendly and produces no poisonous substance. The metal acetate catalysts used for this reaction are discussed in detail. Lithium acetate dihydrate was found to be a novel and efficient catalyst for this reaction. Compared with other metal acetates, lithium acetate dihydrate can attain a maximum catalytic activity at a lower concentration. When the reaction was carried out under the following conditions： the reaction temperature from 230 to 250 ℃, molar ratio of ethylene carbonate（EC） to dimethyl terephthalate（DMT） 3： 1, reaction time 3 h, and a catalyst amount of 0. 4% （molar fraction to DMT）, the yield of dimethyl carbonate（DMC） was 79. 1%.The reaction between ethylene carbonate and dimethyl terephthalate was carried out for the simultaneous synthesis of dimethyl carbonate and poly（ethylene terephthalate）, This reaction is an excellent chemical process that is environmentally friendly and produces no poisonous substance. The metal acetate catalysts used for this reaction are discussed in detail. Lithium acetate dihydrate was found to be a novel and efficient catalyst for this reaction. Compared with other metal acetates, lithium acetate dihydrate can attain a maximum catalytic activity at a lower concentration. When the reaction was carried out under the following conditions： the reaction temperature from 230 to 250 ℃, molar ratio of ethylene carbonate（EC） to dimethyl terephthalate（DMT） 3： 1, reaction time 3 h, and a catalyst amount of 0. 4% （molar fraction to DMT）, the yield of dimethyl carbonate（DMC） was 79. 1%.

关 键 词：Metal acetate Ethylene carbonate Dimethyl terephthalate Dimethyl carbonate Poly（ ethylene terephthalate ） 

分 类 号：O621.256.4[理学—有机化学] O623.624[理学—化学]