带有3个四硫富瓦烯结构单元的三脚型电子给体化合物的合成  

Synthesis of the tripod-type compounds with three TTF units as electronic donor

作　　者：安彩霞[1] 侯瑞斌[1] 金龙一[1] 尹炳柱[1] 

机构地区：[1]延边大学长白山生物功能因子省部共建教育部重点实验室,吉林延吉133002

出　　处：《化学试剂》2007年第4期197-200,共4页Chemical Reagents

基　　金：国家自然科学基金资助项目(20462001)

摘　　要：在DMF-MeOH体系中,2-氰乙硫基-3,6,7-三取代四硫富瓦烯与等物质的量的氢氧化铯作用,生成去保护的3,6,7-三取代四硫富瓦烯-2-硫负离子,后者与三(碘乙基)胺或1,3,5-三(溴甲基)苯反应生成带有3个四硫富瓦烯取代的三脚型电子给体化合物。用NMR、MS和元素分析等手段证实了产物的结构,并用CVs研究了它们的电化学性质。对循环伏安图进行电流微分结果证明,标题化合物的电极反应为分步过程。2-Cyanoethylthio-3, 6, 7-trisubstituted tetrathiaful- valenes entered into reaction with equimolar cesium hydroxide to give 3,6,7-trisubstituted tetrathiafulvalenyl-2-thio anions in the DMF-MeOH solution.The anions could continue to react with tri （ 2- iodoethyl） amine or 1,3,5- tri （bromomethyl） benzene to yield the tripod-type compounds with three TrF units as the electronic donor. Their structure was confirmed by ^1HNMR, MS spectrometry and elemental analysis and their electrochemical behavior was investigated by means of the cyclic voltammetry.The results of differentiation on electric current of CVs showed clearly that the electrode reaction of target compounds was a stepwise process.

关 键 词：四硫富瓦烯 三脚型化合物 三(碘乙基)胺 1 3 5-三溴甲基苯 电化学性质 

分 类 号：O626.2[理学—有机化学]