磁化水技术在电感耦合等离子体-原子发射光谱法中的应用  

The Application of the Magnetic Water Technology to Inductively Coupled Plasma-Atomic Emission Spectrometry

作　　者：周永利[1] 陈金忠[1] 郭庆林[1] 怀素芳[1] 哈静[2] 

机构地区：[1]河北大学物理科学与技术学院,河北省保定市071002 [2]河北农业大学理学院,河北省保定市071001

出　　处：《光谱实验室》2007年第2期64-68,共5页Chinese Journal of Spectroscopy Laboratory

基　　金：河北省科技厅攻关项目(028201801)资助

摘　　要：考察了被测元素谱线强度随磁感应强度的变化情况。在优化磁感应强度0.24T条件下,研究了搅拌条件下样品溶液磁化时间对谱线强度及信背比的影响。经过测量自来水样品中元素Zn、Fe、Mg、(Ⅰ,Ⅱ)、Si、V谱线强度表明,在对水样品进行搅拌磁化时,所测元素的谱线强度及信背比均有所增大;当水样品被磁化处理3h,上述元素的谱线强度分别比未磁化时增加了42.2%、97.9%、10.4%、10.1%、81.2%和28.8%,而且元素Zn、Fe、Si和V的信背比也分别增加了13.8%、86.9%、64%和28.8%,有利于降低光谱分析检出限。Under the optimal magnetic field strength of 0. 24T, both the intensities and the signal-to-background ratio of the measured elements increased. The intensities of Zn,Fe,Mg（ Ⅰ , Ⅱ ）, Si and V in the magnetic water at 3 hours were increased by 42.2%, 97. 9%, 10. 4%, 10. 1 % ,81.2% and 28.8%,respectively, than those of the non-magnetic radiation. The signal-to-background ratio of the elements of Zn,Fe, Si and V are increased about 13.8%, 86.9%, 64 %and 28.8 %,respectively, than that of the non-magnetic radiation. In addition ,the stability of the plasma radiation was improved a little for the magnetic water,and the detection limit was improved.

关 键 词：磁处理技术 电感耦合等离子体-原子发射光谱法 水样品 谱线强度 

分 类 号：O657.31[理学—分析化学]